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Cambridge IGCSE Chemistry · 0620

Chapter 8: The Periodic Table — Part 1

Topic 8.1–8.2, 8.5 · Arrangement, Group I, and noble gases

The Periodic Table Arrangement

  • The Periodic Table is used to classify elements and predict their properties.
  • Elements are arranged in order of increasing atomic (proton) number, in horizontal rows called periods, and vertical columns called groups.
  • Electronic Configuration: Elements in the same group have the same number of outer shell electrons, which results in similar chemical properties.
  • The number of outer shell electrons is equal to the group number (for Groups I to VII), and the number of occupied electron shells is equal to the period number.
  • Metallic and Non-Metallic Character: Metals are found on the left, and non-metals are toward the top right. Metallic character (the tendency to lose electrons) increases down a group and decreases across a period.
  • Group Number and Ion Charge: Elements in Groups I, II, and III (metals) lose electrons to form positive ions with charges of +1, +2, and +3 respectively. Elements in Groups V, VI, and VII (non-metals) gain electrons to form negative ions with charges of -3, -2, and -1.
The Periodic Table showing the arrangement of elements into groups and periods
Diagram 1: The Periodic Table showing the arrangement of elements into groups and periods

Exam Traps

  • Do not confuse period number with group number — sodium (2,8,1) is Period 3, Group I.

Group I: Alkali Metals

  • Group I elements (lithium, sodium, and potassium) are relatively soft metals that can be cut with a knife.
  • Trends down the group:
    • Decreasing melting point: The strength of metallic bonds decreases, requiring less energy to break.
    • Increasing density: While density increases, Group I elements generally have low densities and will float on water.
    • Increasing reactivity: Reactivity increases because atomic radius and electron shielding increase down the group, meaning the outer electron is less strongly attracted to the nucleus and is lost more easily.
  • These trends allow for the prediction of properties of other Group I elements (e.g., rubidium and caesium), which would be expected to be even softer and more reactive.

Exam Traps

  • Lithium reacts less vigorously with water than sodium — do not treat all alkali metals identically.

Group VIII: Noble Gases

  • Group VIII elements (e.g., Argon, Neon) are unreactive, monatomic gases.
  • Stability: They are inert because they possess full outer shells of electrons (8 electrons, except Helium which has 2).
  • Because they have a stable electronic configuration, they do not need to lose or gain electrons, making them very stable and unreactive.

Exam Traps

  • Helium has 2 outer electrons, not 8 — do not apply the eight-electron rule to helium.

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